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32 2 Cyclization of 2,3-Oxidosqualene – The First Committed Step in Triterpenoid Biosynthesis . . . . . . . . . . . 1 Resolution of Cyclase Activities Required for Sterol and Triterpenoid Biosynthesis . . . . . . . . Cloning of 2,3-Oxidosqualene Cyclases . . . . . OSCs Required for Sterol Biosynthesis . . . . . . Triterpenoid Cyclases . . . . . . . . . . OSC Gene Families . . . . . . . . . . . The Relationship Between Structure and Function .

46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. Biosynthesis of Triterpenoid Saponins in Plants 49 77. Paczkowski C, Wojciechowski ZA (1994) Phytochemistry 35:1429 78. Kintia PK, Wojciechowski Z, Kasprzyk Z (1974) Bulletin de L’Académie Polonaise des Sciences 22:73 79. Wojciechowski ZA (1975) Phytochemistry 14:1749 80. Bergenstråhle A, Tillberg E, Jonsson L (1992) Plant Sci 84:35 81. Kalinowska M, Wojciechowski ZA (1986) Phytochemistry 25:2525 82.

Fenwick GR, Price KR, Tsukamota C, Okubo K (1992) Saponins. In: D’Mello JP, Duffus CM, Duffus JH (eds) Toxic substances in crop plants. The Royal Society of Chemistry, Cambridge, UK, p 284 9. Hostettmann KA, Marston A (1995) Saponins. Chemistry and pharmacology of natural products. Cambridge University Press, Cambridge, UK 10. Roddick JG (1974) Phytochemistry 13:9 11. Osbourn AE (1996) Trends Plant Sci 1:4 12. Kushiro T, Shibuya M, Ebizuka Y (1998) Eur J Biochem 256:238 13. Kushiro T, Ohno Y, Shibuya M, Ebizuka Y (1997) Biol Pharm Bull 20:292 14.

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