Advances in catalysis by W G Frankenburg; V I Komarewsky; Eric K Rideal PDF

By W G Frankenburg; V I Komarewsky; Eric K Rideal

ISBN-10: 0080565077

ISBN-13: 9780080565071


content material: entrance hide; Advances in Catalysis and similar topics, quantity III; Copyright web page; Contents; individuals to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. creation; II. The Multiplet thought; III. dialogue of the idea; IV. Steric concerns in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically energetic Solids; I. creation; II. normal ideas; III. Experimental tools; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. similar platforms; XI. Self-Supported platforms; XII. Ferromagnetism; XIII. identity of Ferromagnetic levels; XIV. response approaches; XV. answer procedures; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. creation; II. situation of Air and Acetylene; III. Acetylene removing; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation through Silver Nitrate; References; bankruptcy four. The Poisoning of metal Catalysts I. Catalysts vulnerable to PoisoningII. primary varieties of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. extra elements Influencing Toxicity; V. important Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. creation; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. dimension of the "Acidity" of Cracking Catalysts; III. identity of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response premiums and Selectivity in Catalyst Pores; I. advent; III . The actual photo of the Pore constitution; III. Mechanism of shipping in Catalyst Pores; IV. actual components selecting response charges on Porous Catalysts . (Definition of fee Constants, the basic Differential Equation and the legislation of Conservation of Mass V. response premiums in unmarried PoresVI. response premiums on useful Catalyst Pellets; VII. response premiums on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impression of Pore constitution on Catalyst Selectivity; Appendix; thesaurus of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. creation; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. coaching of Nickel Sulfide Catalysts; VII. worthwhile lifestyles and Regeneration
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Seriously influenced by this factor, but for large, highly magnetic samples the possible diminution of the field should be considered. IV. THE SUSCEPTIBILITY ISOTHERM* Since 1946 there has been in process of development a t Northwestern University a new method for the elucidation of structure in certain classes of catalytically active inorganic solids. This method depends upon an application of magnetic moment and molecular field theory t o the oxidation state, coordination, and atomic environment of the active element.

1. Preparation.. . . . . ............................ 2. Susceptibility Data.. . IX. Supported Copper Oxide.. 1. Preparation.. 2. Susceptibility Data. ............................ 3. Activity Data . . . . . . . . . . . . . . . . . . . . . . . . . X. Related Systems . . . . . . . . . . . . . . . . . . . . . . . . . XI. Self-supported Systems. 1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . 28 32 33 33 36 41 41 42 48 50 52 52 53 59 63 66 66 69 72 73 74 * A large portion of this review is based on the author’s papers in the Journal of the American Chemical Society.

And Teis, R. , Compt. rend. acad. sci. R. S. S . 63, 715 (1946). 47. 36, 917 (1939) 48. , J . Am. Chem. 64, 2661 (1932). 49. , Sci. Papers Inst. Phys. Chem. Research (Tokyo) 29, 223 (1936). 50. Twigg, G. , and Rideal, E. , Trans. 36, 533 (1940). 51. Herington, E. F. , and Rideal, E. , Proc. Roy. Soc. (London) A184, 434, 447 (1947)52. Craxford, S. , Trans. 36, 946 (1939). 53. Craxford, S. , and Rideal, E. , J . Chem. 1939, 1604. 54. Herington, E. F. , Trans. 37, 361 (1941). 55. Herington, E. F.

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Advances in catalysis by W G Frankenburg; V I Komarewsky; Eric K Rideal

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