By Craig A. Bayse, Julia L. Brumaghim
Biochalcogen Chemistry: The organic Chemistry of Sulfur, Selenium, and Tellurium highlights the organic makes use of of heavy chalcogens as a key region of concentration in bioinorganic chemistry and a unifying topic for examine in a wide selection of disciplines. fresh achievements in those multidisciplinary efforts are awarded that debate the delicate, but vital roles of biochalcogens in dwelling platforms as sulfur- and selenium-containing metabolic intermediates and items (Chapters 1 and 10) and of their oxidation while coordinated to metals (Chapters three and 4). Chemical and instrumental instruments for detecting sulfur and selenium species and their functionalities also are mentioned (Chapters 2 and 6), as are new instructions in biochalcogen purposes to redox scavenging, either when it comes to synthesis (Chapters 7 and eight) and mechanistic modeling (Chapter 9). Tellurium, with out typical organic functionality, is represented including sulfur and selenium as a phasing agent in nucleic acid crystallography and for different organic reviews (Chapter 5).
This ebook will function an invaluable choice of experiences and learn leads to this different box, encompassing learn in bioinorganic chemistry, natural synthesis, computational techniques, and biochemistry, as an thought for researchers wishing to go into the range of fields that surround those multidisciplinary study efforts, and as an invaluable source for undergraduate or graduate classes concentrating on major team and transition aspect biochemistry. a large viewers will locate this ebook a useful source for this swiftly increasing field.
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Extra resources for Biochalcogen Chemistry: The Biological Chemistry of Sulfur, Selenium, and Tellurium
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Concluded that alkyl substitution of the thione ligand, even if increasing thione nucleophilicity, did not improve the donor ability of the thione ligand. 54 µM (93). These effects were consistent with the cytotoxicity of other Cu-phen complexes and proposed to occur through oxidative damage to DNA and other cellular targets. Figure 10. Crystal structures of A) trans-Cu(dmit)2I (19), B) cis-Cu(dmit)2I (19), C) Tp*Cu(dmit) (14), and D) [Cu(dmit)3][OTf] (20). Hydrogen atoms and counterions are omitted for clarity.
Biochalcogen Chemistry: The Biological Chemistry of Sulfur, Selenium, and Tellurium by Craig A. Bayse, Julia L. Brumaghim