By George W Gokel
Guide offers complete assurance of natural chemistry; together with sensible details, key equations and tables, and a radical creation to every subject. Revised to incorporate 50% new content material. prior variation: c1987.
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Additional resources for Dean's handbook of organic chemistry
Locants are added if necessary. For example, Ester groups in R1 ˆ CO ˆ OR2 compounds are named (1) by the prefix alkoxycarbonylor aryloxycabonyl- for ˆ CO ˆ OR2 when the radical R1 contains a substituent with priority for citation as principal group or (2) by the prefix acyloxy- for R1 ˆ CO ˆ O ˆ when the radical R2 contains a substituent with priority for citation as principal group. Examples are The trivial name acetoxy is retained for the CH3 ˆ CO ˆ O ˆ group. Compounds of the type R2C(OR2)3 are named as R2 esters of the hypothetical ortho acids.
Indicated hydrogen, whether cited in the name or omitted as being conventional. 2. 7. 3. Multiple bonds in acyclic compounds; in bicycloalkanes, tricycloalkanes, and polycycloalkanes, double bonds having priority over triple bonds; and in heterocyclic systems whose names end in -etine, -oline, or -olene. 4. The lowest-numbered locant for substituents named as prefixes, hydro prefixes, -ene, and -yne, all considered together in one series in ascending numerical order. 5. The lowest locant for that substituent named as prefix which is cited first in the name.
Replacement nomenclature is intended for use only when other nomenclature systems are difficult to apply in the naming of chains containing heteroatoms. When no group is present that can be named as a principal group, the longest chain of carbon and heteroatoms terminating with carbon is chosen and named as though the entire chain were that of an acyclic hydrocarbon. 3. Locants indicate the positions of the heteroatoms in the chain. Lowest-numbered locants are assigned to the principal group when such is present.
Dean's handbook of organic chemistry by George W Gokel