Download e-book for iPad: Synthesis of Saturated Oxygenated Heterocycles I: 5- and by Janine Cossy

By Janine Cossy

ISBN-10: 3642414729

ISBN-13: 9783642414725

ISBN-10: 3642414737

ISBN-13: 9783642414732

The sequence subject matters in Heterocyclic Chemistry provides serious stories on current and destiny traits within the examine of heterocyclic compounds. total the scope is to hide subject matters facing all components inside of heterocyclic chemistry, either experimental and theoretical, of curiosity to the final heterocyclic chemistry group. The sequence involves subject comparable volumes edited by way of well known editors with contributions of specialists within the field.

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Additional resources for Synthesis of Saturated Oxygenated Heterocycles I: 5- and 6-Membered Rings

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44 46 46 52 56 59 61 61 62 70 73 76 76 77 79 81 81 82 85 85 87 88 91 91 92 Abstract Tetrahydropyran (THP) rings are important motifs in biologically active molecules. A. D. Rychnovsky (*) • N. edu J. A. Perry et al. Table 1 Comparison of the frequency and median yields for the disconnections discussed in this survey Disconnection O1–C2 C2–C3 C3–C4 Others Strategy Conjugate addition Nucleophilic substitution cyclization Alkene-mediated cyclization Epoxide opening Prins cyclization Petasis–Ferrier union/rearrangement Panek annulation Class 1 ring-closing metathesis Class 2 ring-closing metathesis Hetero-Diels–Alder Lactol reduction Lactone reduction/reductive acetylation n 14 10 8 2 13 3 4 5 3 8 4 13 Median % yield 75 84 81 82 68 77 78 94 73 69 95 84 typical retrosynthetic disconnections.

3 Panek [4+2]-Annulation Strategies . . . . . . . . . . . . . . . . . . . . . . . . . . 4 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 C3–C4 THP-Forming Processes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Class 1 Ring-Closing Metathesis . . . . . . . . . . . . . . . . . . . . . .

5 O1–C6 and C2–C3 DHP-Forming Processes . . . . . . . . . . . . . . . . . . . . . . . . 1 Hetero-Diels–Alder (HDA) Reactions . . . . . . . . . . . . . . . . . . . . . . . . . 2 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 C2 Functionalization of Lactols and Lactones . . . .

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Synthesis of Saturated Oxygenated Heterocycles I: 5- and 6-Membered Rings by Janine Cossy


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